Alex Oxlade-Chamberlain sent England in front in the 11th minute after being set up by the first of Ben Chilwell’s three assists. The left back’s next two — a free kick and corner — were completed by Kane’s headers.
After Marcus Rashford netted on the half-hour, Kane completed his second consecutive Wembley hat trick with a close-range finish in the 37th minute to take his England haul to 31 goals.
After a flood of goals in the first half, the Montenegro net was only breached after the break by Aleksandar Sofranac’s own-goal and Abraham in the 84th.
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